Details

Modern Organonickel Chemistry


Modern Organonickel Chemistry


1. Aufl.

von: Yoshinao Tamaru

183,99 €

Verlag: Wiley-VCH (D)
Format: PDF
Veröffentl.: 06.03.2006
ISBN/EAN: 9783527604234
Sprache: englisch
Anzahl Seiten: 346

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Beschreibungen

Organonickel chemistry plays an increasingly important role in organic chemistry, and interest in this topic is now just as keen as in organopalladium chemistry. While there are numerous, very successful books on the latter, a book specializing in organonickel chemistry is long overdue.<br> Edited by one of the leading experts in the field, this volume covers the many discoveries made over the past 30 years, and previously scattered throughout the literature. Active researchers working at the forefront of organonickel chemistry provide a comprehensive review of the topic, including cross-coupling reactions, asymmetric synthesis and heterogeneous catalysis reaction types.<br> A must-have for both organometallic chemists and synthetic organic chemists.
Introductory Guide to Organonickel Chemistry<br /> Nickel-catalyzed Cross-coupling Reactions<br /> Reaction of Alkenes and Allyl Alcohol Derivatives<br /> Reaction of Alkynes<br /> The Reaction of Dienes and Allenes<br /> Cyclooligomerization and Cycloisomerization of Alkenes and Alkynes<br /> Nickel-mediated and -catalyzed Carboxylation<br /> Carbonylation and Decarbonylation<br /> Asymmetric Synthesis<br /> Heterogeneous Catalysis
"This book provides knowledge and information on high quality, both in the chapter introductions and in the descriptions of recent developments in organonickel chemistry. The arrangement of the chapter topics is good, and there are no overlaps. ... The book can be recommended for organic chemists, both in universities and in industrial research and development. ...students in advanced courses will benefit from studying the metal-catalyzed reactions that are discussed in Modern Organonickel Chemistry, and the book will certainly give them a good introduction to the world of metalcatalyzed organic synthetic chemistry."<br /> Angewandte Chemie<br />
Born in 1945, Yoshinao Tamaru studied chemistry at Kyoto University, Japan, where he completed his doctoral thesis on the "New Aspects of Thio-bicyclic Chemistry" under Professor Z. Yoshida in 1973. That same year he joined the University's Department of Applied Chemistry as an assistant, becoming an associate professor in 1981. During this period, he spent a year as a postdoctoral fellow in the working group of Professor Barry M. Trost at the University of Wisconsin. In 1989 he took up a chair at the Department of Applied Chemistry at Nagasaki University. Among others, Professor Tamaru is a recipient of the Young Chemist Award, given by Chemical Society of Japan. His current research interests include developing new methodologies based on transition metal catalysis utilizing organozincs, organo-boranes, and nitrogen and sulfur heteroatoms as well as modified enzymes as catalysts for organic transformation.
The use of nickel in organic chemistry significantly smoothes the progress of many reactions. Like many of its much more expensive counterparts, such as palladium and platinum, nickel catalyzes many unique reactions and thus enormously widens the scope in organic chemistry.<br /> Over the past few years, interest in this topic has grown such that it is now just as keen as that in organopalladium chemistry. Yet while there are numerous, very successful books on the latter, a book specializing in organonickel chemistry is long overdue.<br /> Edited by one of the leading experts in the field, this volume covers the many discoveries made over the past 30 years, and previously only scattered throughout the literature. Active researchers working at the forefront of organonickel chemistry provide a comprehensive review of the topic, including:<br /> * Nickel-catalyzed Cross-coupling Reactions<br /> * Reaction of Alkenes including Allylnickel Complexes<br /> * Reaction of Alkynes<br /> * Reaction of Dienes and Allenes<br /> * Cycloisomerization<br /> * Carbonylation and Carboxylation<br /> * Asymmetric Synthesis<br /> * Heterogeneous Catalysis<br /> The result is an essential authoritative work for both organometallic chemists and synthetic organic chemists.<br />

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